High Resolution Fourier Transform Raman Spectroscopy of Gases

J. Bendtsen
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Abstract

Raman spectra of molecules in the gasphase yield information about the energy of the rotational and the rotational-vibrational states. This information may more easily be obtained from absorption spectroscopy in the microwave and infrared region, but the less restricted selection rules governing the Raman transitions yield information not measureable in absorption.
气体的高分辨率傅里叶变换拉曼光谱
气相分子的拉曼光谱给出了旋转态和旋转-振动态的能量信息。这些信息可以更容易地从微波和红外区域的吸收光谱中获得,但是控制拉曼跃迁的较少限制的选择规则产生的信息在吸收中无法测量。
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