Surface structure changes in cement paste exposed to 10.6μm laser radiation

J. J. Soto-Bernal, M. R. Moreno-Virgen, C. Frausto-Reyes, A. Bonilla-Petriciolet, J. Vega-Durán, J. Pineda-Piñón, J. A. Ortiz-Lozano
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Abstract

We report the changes occurring in cement pastes irradiated by 10.6μm CO2 laser at different stages of hydration. Raman spectroscopy, X-rays and Scanning Electronic Microscopy (SEM) techniques had been used to observe molecular structural changes. Intensity of cement paste Raman peaks after laser irradiation was monitored in samples irradiated 2, 3, 4, 5, 6, 7, 8, 9, 10 and 11 days after their preparation. Applied laser power changed Raman peaks intensity at 187.5cm-1, 563cm-1, 695cm-1, 750cm-1, 897cm-1, 1042cm-1 and 1159cm-1 that corresponds to compounds already presents in cement pastes. X ray diffraction and SEM images confirm the recrystalization of cement paste compounds into new phases (alite and belite) after irradiation. The produced changes show a clear dependence on the applied laser power density and age of samples.
10.6μm激光辐照下水泥浆体表面结构的变化
本文报道了10.6μm CO2激光辐照水泥浆体在水化不同阶段的变化。利用拉曼光谱、x射线和扫描电子显微镜(SEM)技术观察分子结构变化。在制备后第2、3、4、5、6、7、8、9、10和11天,对激光照射后水泥浆体拉曼峰强度进行监测。施加的激光功率改变了187.5cm-1、563cm-1、695cm-1、750cm-1、897cm-1、1042cm-1和1159cm-1的拉曼峰强度,对应于水泥浆中已经存在的化合物。X射线衍射和扫描电镜图像证实辐照后水泥浆体化合物重结晶为新相(阿利石和贝来石)。所产生的变化明显依赖于所施加的激光功率密度和样品的年龄。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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