Analytical application of H 2 O 2 -induced chiroptical graphitic carbon dots

Abstract

Carbon dots (CDs) have emerged as efficient peroxidase mimics in recent years. However, to further increase its efficiency as peroxidase-mimic, it is also desirable to understand the modification of CD’s geometry during the catalytic reaction. Herein, we focused on the change in material property of the CDs upon their reaction with H2O2 during the peroxidase reaction. D-(+)-glucose was transformed into chiroptical CDs bearing peroxidase-like activity and can be used to detect H2O2 with a limit of detection of 630 μM. The addition of H2O2 to the CDs resulted in its increased molecular orderliness leading to the introduction of polycrystallinity without affecting its peroxidase-like activity.