Polymer formation in conductive Mg-doped C60 films

N. Kojima, S. Nishi, C. Morales, M. Yamaguchi
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Abstract

Mg-doping in a C60 layer is expected to improve the electrical conduction in organic solar cells. However, the mechanism of conductivity improvement and the detailed structure of Mg-doped C60 material are still unclear. In this study, we investigated the vibrational spectra to understand structural change in Mg-doped C60 in terms of the bonding state of the adjacent C60 molecules. IR spectra can be explained by several types of C60 polymer formation in Mg-doped C60 even with the low Mg concentration. It is thought that the existence of several types of short length C60 polymers cause the crystal quality degradation.
导电掺镁C60薄膜中聚合物的形成
在C60层中掺杂mg有望改善有机太阳能电池的导电性。然而,掺杂mg的C60材料电导率提高的机理和详细结构尚不清楚。在这项研究中,我们研究了振动光谱,以了解镁掺杂C60的结构变化,根据相邻C60分子的成键状态。在低Mg浓度的C60中,可以用几种类型的C60聚合物的形成来解释红外光谱。认为几种短长度C60聚合物的存在是导致晶体质量下降的原因。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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