Synthesis and application of bonding agents used in rocket propellants

D. Dundar, M. Gullu, M. Ak, G. Puskulcu, C. Yildirim
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引用次数: 2

Abstract

In this research work, utilisation of new bonding agents, synthesised from cheap and easily available starting materials, have been investigated in composite rocket propellants and liners in place of widely used aziridine and amine based bonding agents (MAPO, HX-752, TEPANOL). The performance properties of propellants and liners prepared with these compounds have been examined. Some simple alkyl hydantoins (AH1, AH2, AH3) and their N-alkyl and N,N-dialkyl derivatives (HT1, HT2, HT3, HT4, HT5) have been synthesised in laboratory scale and structurally identified in the first step. Later, some of the selected hydantoin derivates have been used as bonding agents in the preparation of propellants and liners. Twelve propellant samples and eight liner samples have been subjected to some physical and mechanical tests which are generally used for the examination of rocket propellants and liners. Most of the propellants and liners have shown good physical and mechanical performance properties, except ones which were prepared with hydantoins containing morpholino groups. In addition physical and mechanical tests, some of the propellants have been used in Ballistic Research Motor (BRM) tests and shown perfect results.
火箭推进剂用粘结剂的合成与应用
在这项研究工作中,利用廉价和容易获得的起始材料合成的新型粘合剂,研究了复合火箭推进剂和衬垫中取代广泛使用的氮吡啶和胺基粘合剂(MAPO, HX-752, TEPANOL)。研究了用这些化合物制备的推进剂和衬垫的性能。一些简单的烷基酰脲(AH1、AH2、AH3)及其N-烷基和N,N-二烷基衍生物(HT1、HT2、HT3、HT4、HT5)已在实验室规模下合成并初步鉴定了结构。后来,一些选定的氢妥英衍生物被用作粘合剂,用于制备推进剂和衬垫。对12个推进剂样品和8个衬里样品进行了一些通常用于火箭推进剂和衬里检验的物理和力学试验。大多数推进剂和衬垫都表现出良好的物理和机械性能,除了用含有morpholino基团的氢酰脲制备的推进剂和衬垫外。除物理和力学试验外,部分推进剂已用于弹道研究发动机(BRM)试验,并显示出良好的效果。
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