Optimization of Pelleting Parameters for Producing Composite Pellets Using Zeolitic Material From Fly Ash

D. Fungaro, T. Bertolini
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Abstract

Zeolitic material in powder form was prepared from fly ash by direct activation treatment. The resulted fly ash-based zeolite was pelletizing and the effect of different inorganic (calcium hydroxide, bentonite, kaolinite) and organic (dextrin) binders with varying percentage was investigated. The zeolitic materials were analyzed by XRF, XRD, SEM, FTIR, TG-DTG and Nitrogen adsorption/desorption isotherm. Compression and impact tests have been used to study the deformation and breakage behaviour of spherical granules. The best performance was obtained by zeolite granular containing 5 wt.% bentonite and 5 wt.% kaolinite with mechanical strength and satisfactory water resistance. The synthesis of pelletized zeolite from by-products derived from coal combustion provides not only environmental and economic benefits, but also contributes to achieving the principles of sustainable development.
粉煤灰沸石制备复合球团的制球参数优化
以粉煤灰为原料,采用直接活化法制备了粉末状沸石材料。研究了不同无机(氢氧化钙、膨润土、高岭土)和有机(糊精)粘结剂配比对粉煤灰基沸石成球性能的影响。采用XRF、XRD、SEM、FTIR、TG-DTG和氮气吸附/脱附等温线对沸石材料进行了分析。采用压缩和冲击试验研究了球形颗粒的变形和破坏行为。沸石颗粒中膨润土和高岭石的含量分别为5 wt.%和5 wt.%,具有良好的机械强度和耐水性。利用煤燃烧副产物合成成球沸石不仅具有环境效益和经济效益,而且有助于实现可持续发展的原则。
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