Effect of Different Waste Coal Ash (WCA) Loading to Dynamic Load Application of Chloroprene Rubber

H. E. A. Maulod, N. Mohamad, J. Razak, Ahmad Aqlan Mohd Rosedi, A. Andriyana, Nurzallia Mohd Saad, M. H. Flaifel
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Abstract

This study seeks to address the effect of waste coal ash collected from burnt charcoal after human recreational activities to the chloroprene rubber’s dynamic property specifically in cyclic load. Waste coal ash was chosen due to their availability, low cost, and recyclability. The waste coal ash was incorporated into chloroprene rubber via melt compounding process using an internal mixer. The compounding formulation of the chloroprene rubber compound and coal ash were based on 100 phr of the chloroprene rubber. The loading of waste coal ash were varied at 5, 10, 20, 30 and 40 phr. Waste coal ash exhibits the highest reinforcing property at 40 phr loading. The fatigue test was done to determine the peak stress value and stress softening effect and found that at 5 – 30 phr waste coal ash had a detrimental effect on CR compound while at 40phr, the rubber compound exhibit positive result with an increase of 30% of the peak stress. Morphological study using scanning electron microscopy (SEM) showed degrees of agglomeration of the waste coal ash in the chloroprene rubber matrices. The dispersion of waste coal ash agglomerates and morphology of failures were in good agreement with the observed dynamic properties.
不同废煤灰掺量对氯丁橡胶动载性能的影响
本研究旨在探讨人类娱乐活动后燃烧木炭收集的废煤灰对氯丁橡胶动态性能的影响,特别是在循环载荷下。选择废煤灰是因为其可获得性、低成本和可回收性。利用内混炼机将废煤灰与氯丁橡胶进行熔体复配。以100phr的氯丁橡胶为基础,确定了氯丁橡胶胶料与粉煤灰的复合配方。在5、10、20、30和40 phr的不同负荷下,粉煤灰的掺量不同。在负荷为40phr时,废粉煤灰的增强性能最高。通过疲劳试验确定了峰值应力值和应力软化效果,发现在5 ~ 30 phr时废煤灰对CR胶料有不利影响,而在40phr时,橡胶胶料表现出积极效果,峰值应力提高了30%。利用扫描电镜(SEM)对废煤灰在氯丁橡胶基体中的结块程度进行了形态学研究。废煤灰团块的分散和破坏形态与观测到的动力特性吻合较好。
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