Physico-chemical properties new nitrogen- and phosphorus containing ion exchange resine on the base of polyvinylchloride

D. Bekchanov, M. Mukhamediev, D. Gafurova
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引用次数: 1

Abstract

Peculiarities of the interaction of PPE-1 anion exchange resin with phosphonic acid production based on granular polyvinyl chloride were studied. As a result of the modification, a polyampholite was obtained in terms of physicochemical properties not inferior to the industrial polyampholite APFC-45. We also investigated the sorption of copper (II), nickel (II) and indium (III) ions on a polyampholite based on granular polyvinylchloride. The dependence of static adsorption on aqueous solutions on the concentration of metal ions and the temperature of the system is established. Isotherms were constructed and found the adsorption equilibrium constants, the thermodynamic parameters of the process isobaric isothermal potential (∆G), enthalpy (∆H) and entropy (∆S). It is shown that the investigated sorbent absorbs ions Cu (II) to a greater extent than the other ions.
聚氯乙烯基新型含氮磷离子交换树脂的理化性质
研究了pe -1阴离子交换树脂与颗粒聚氯乙烯合成膦酸的相互作用特性。经改性后得到的聚酰亚胺的理化性能不低于工业用聚酰亚胺APFC-45。我们还研究了铜(II)、镍(II)和铟(III)离子在基于粒状聚氯乙烯的聚酰胺上的吸附。建立了金属离子浓度和体系温度对水溶液静态吸附的依赖关系。建立等温线,求出吸附平衡常数、过程等温势(∆G)、焓(∆H)和熵(∆S)的热力学参数。结果表明,所研究的吸附剂对Cu (II)离子的吸收率高于其他离子。
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