Comparative Evaluation of Dual Emission Mode for Yellowish-Green Borophosphate-Based Solid Solution La 7O 6(BO 3)(PO 4) 2:Er

Zhigang Cai, Dan Yang, Zhuohui Zhang, Xinchen Ge, Yuchuan Luo, Youkui Zheng, Z. Fang, Jing Zhu
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Abstract

To acquire visible emissions using near-ultraviolet (NUV) and near-infrared (NIR) irradiations for multiple solid state lighting and display applications, exploring efficient upconversion (UC)/downconversion (DC) mode of erbium ion in different matrixes is of great importance. Here, we aimed to originally study the dual emission mode of borophosphate La7O6(BO3)(PO4)2 (LBP)-based solid solution doped with erbium ion. Er3+ occupies the lattice site of La3+ . A yellowish-green light is acquired by both DC and UC. It is identified that the UC photoluminescence has lower correlated color temperature (5694 K), higher color purity (87%), and longer lifetime (0.338 ms) than the DC. The present research can provide a new insight into the design and UC/DC photoluminescence of borophosphate-based solid solution fabricated by erbium for expanding solid state lighting applications.
黄绿色硼磷酸盐基固溶体la706 (bo3)(po4) 2:Er双发射模式的比较评价
为了利用近紫外(NUV)和近红外(NIR)辐射获取多种固态照明和显示应用的可见辐射,探索不同基质中铒离子的高效上转换(UC)/下转换(DC)模式具有重要意义。在这里,我们最初的目的是研究掺杂铒离子的硼磷酸盐La7O6(BO3)(PO4)2 (LBP)基固溶体的双发射模式。Er3+占据了La3+的晶格位置。DC和UC均获得黄绿色光。结果表明,UC光致发光具有较低的相关色温(5694 K)、较高的色纯度(87%)和较长的寿命(0.338 ms)。本研究为铒制备的硼磷酸酯基固溶体的设计和UC/DC光致发光提供了新的思路,为扩大固态照明应用提供了新的思路。
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