{"title":"Mechano(-)Synthesis","authors":"Lorentz Jäntschi, Sorana D. Bolboacă","doi":"10.1201/9780429022944-25","DOIUrl":null,"url":null,"abstract":"Mechano(-)synthesis refers a hypothetical chemical synthesis in which reaction outcomes are determined by the use of mechanical constraints to direct reactive molecules to specific molecular sites. In a Mech-synth process reactive molecules would be attached to molecular mechanical systems, and their encounters would result from mechanical motions bringing them together in planned sequences, positions, and orientations. Mech-synth strongly favoring desired reactions by holding reactants together in optimal orientations for many molecular vibration cycles. In biology, the ribosome provides an example of a programmable Mech-synth device. There are presently no chemical syntheses which fully achieve this aim. Some atomic placement has been achieved with scanning tunnelling microscopes.","PeriodicalId":268564,"journal":{"name":"New Frontiers in Nanochemistry","volume":"3 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2020-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Frontiers in Nanochemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1201/9780429022944-25","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Mechano(-)synthesis refers a hypothetical chemical synthesis in which reaction outcomes are determined by the use of mechanical constraints to direct reactive molecules to specific molecular sites. In a Mech-synth process reactive molecules would be attached to molecular mechanical systems, and their encounters would result from mechanical motions bringing them together in planned sequences, positions, and orientations. Mech-synth strongly favoring desired reactions by holding reactants together in optimal orientations for many molecular vibration cycles. In biology, the ribosome provides an example of a programmable Mech-synth device. There are presently no chemical syntheses which fully achieve this aim. Some atomic placement has been achieved with scanning tunnelling microscopes.