Detector Nonlinearity Related Errors in Fourier Transform Spectroscopy and their Correction

L. Hanssen, C. J. Zhu, Z. Zhang
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Abstract

Due to the relatively high flux levels available in FT-IR spectrophotometers and the universal need for better signal to noise ratios, detectors are often operated in conditions under which their responsivity varies during the measurement. This can happen both during a single measurement (nonlinearity) as well as between measurements (nonequivalence). The results of measurements made under these conditions will contain errors. The quantity and spectral distribution of the errors will depend on both the instrument signature and the sample properties under investigation.
傅里叶变换光谱中探测器非线性相关误差及其校正
由于FT-IR分光光度计中可用的相对较高的通量水平以及对更好的信噪比的普遍需求,探测器通常在其响应率在测量期间变化的条件下操作。这既可以发生在单次测量期间(非线性),也可以发生在两次测量之间(非等效)。在这些条件下进行的测量结果将包含误差。误差的数量和光谱分布将取决于仪器特征和所研究的样品性质。
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