Phase Composition, Microstructure, Surface Hardness, and Corrosion Resistance of Surface Plasma Gas Nitrided Titanium Alloy Ti-10V-2Fe-3Al with Indirect Plasmatron

D. Veselinov, H. Skulev
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Abstract

This study investigates and analyzes the influence of plasma gas nitriding with indirect plasmatron on the phase transformations, microstructure, surface microhardness, and corrosion resistance of titanium alloy Ti-10V-2Fe-3Al. In order to achieve this, the limits of the power used in this process are a minimum of 12 kW and a maximum of 35 kW. The thermochemical treatment time intervals are set at 5, 10, and 15 min. It is found that the phase composition of the surface layer after plasma gas nitriding consists of α-Ti, (N, O), TiN, and TiO2. Titanium oxides are detected only on the outermost surface of the nitrided layers. The measured hardness of the plasma gas nitrided layers obtained of Ti-10V-2Fe-3Al is up to 650 HK0.05. Potentiodynamic polarization analysis indicates that the subjects nitrided using 18 kW of power for 15 min have the lowest corrosion rate, while the highest corrosion rate is observed in those nitrided at 25 kW for 15 min.
间接等离子体气体氮化Ti-10V-2Fe-3Al钛合金的相组成、显微组织、表面硬度及耐蚀性
研究分析了间接等离子体气体氮化对Ti-10V-2Fe-3Al钛合金相变、显微组织、表面显微硬度和耐蚀性的影响。为了实现这一点,在这个过程中使用的功率限制是最小12千瓦和最大35千瓦。热化学处理时间间隔分别设置为5、10、15 min。结果表明,等离子体气体氮化后的表层相组成为α-Ti、(N, O)、TiN和TiO2。钛氧化物仅在氮化层的最外层被检测到。Ti-10V-2Fe-3Al等离子体气体氮化层的硬度可达650 HK0.05。电势极化分析表明,功率为18 kW、时间为15 min的腐蚀速率最低,功率为25 kW、时间为15 min的腐蚀速率最高。
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