Valorization of waste cooking oil into bio-sourced products

H. Chenni, M. Djeghballou, S. Daba, N. Outili, A. H. Meniai
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Abstract

Waste cooking oil is produced in large quantities and disposed of in the environment, hence the interest of many researchers on its valorization using conversion of waste materials into different bio-products. Among the possibilities of bio-products, the present work investigates epoxide and polyol synthesis from waste oil. These renewable-products represent an alternative to petroleum-based ones with different application in polymeric sectors. The objective of this work is to value a waste by converting it to a bio-based product with an added value using an eco-friendly process that generates less waste or by-products. The produced epoxidized waste cooking oil had an oxirane value of 7.23% and a density of 0.992 g/cm3, it was transformed into bio-based polyol with an hydroxyl number of 45.02 mg KOH/g and a height density of 1.056 g/ cm3. The obtained yields of the two reactions was 92% and 100% for epoxidation and hydroxylation respectively.
废弃食用油转化为生物源产品的研究
废弃食用油是大量生产并在环境中处理的,因此许多研究人员对利用废物转化为不同生物产品来实现其增值感兴趣。在生物制品的可能性中,本工作研究了废油合成环氧化物和多元醇的可能性。这些可再生产品代表了石油基产品的替代品,在聚合物领域有不同的应用。这项工作的目标是通过使用产生更少废物或副产品的环保过程将废物转化为具有附加值的生物基产品来评估废物的价值。所得环氧化废食用油的环氧烷值为7.23%,密度为0.992 g/cm3,转化为羟基数为45.02 mg KOH/g,高度密度为1.056 g/cm3的生物基多元醇。环氧化和羟基化反应的产率分别为92%和100%。
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