Soybean Oil-based Biodiesel Production Catalyzed with Na2O/Al2O3

Yingming Chen, Xiaodong Chen, Junhua Peng
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引用次数: 3

Abstract

Solid alkali catalyst was prepared with CH3COONa immobilized on alumina by impregnation method. Represented with SEM, IR and BET techniques, the catalysts indicated relatively uniform particle size distribution with perfect particle surface area, pore volume and pore size. Soybean oil was catalyzed to investigate the catalysis characteristics. The results showed that the maximum conversion rate of 85.4% was obtained under the optimal reaction conditions: alcohol/oil molar ratio of 9:1, 65°C, 3 hours, 2wt% catalyst. The catalyst could be reused with half-life of 7 times. The major components of biodiesel are mixture of C17 and C19 unsaturated fatty acid methyl esters.
Na2O/Al2O3催化生产大豆油基生物柴油
采用浸渍法制备了固载于氧化铝上的CH3COONa固体碱催化剂。通过SEM、IR和BET等技术表征,催化剂粒径分布较为均匀,颗粒表面积、孔体积和孔径均较为理想。以大豆油为催化剂,研究其催化特性。结果表明,在醇油摩尔比为9:1、反应温度为65℃、反应时间为3 h、催化剂质量分数为2wt%的条件下,反应转化率最高可达85.4%。催化剂可重复使用,半衰期为7次。生物柴油的主要成分是C17和C19不饱和脂肪酸甲酯的混合物。
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