Using The Electrochemical Etching as A Method for The Preparation of The Titanium Surface to Get Anodic Oxide Films

O. Savvova, G. Voronov, O. Fesenko, O. Smirnova, Kostiantyn Zhukov, O. Pylypenko
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Abstract

The polarization investigations of the anode behavior of titanium in mixed organic-&-aqueous fluoride-containing electrolytes have been carried out. The polarization curves constructed for electrode processes allow us to draw a conclusion that the simultaneous behavior of several processes is possible in the specified electrolytes and these processes include chemical etching of metal due to its interaction with solution components, electrochemical dissolution under polarization conditions and the formation of the oxide film due to the anode oxidation. The prevalence of one or other type of the process in this case is defined by the electrolyte composition and the electric electrolysis parameters. The obtained data serve as a basis for the development of the new method of combined etching that provides the homogenization of the titanium surface with simultaneous elimination of toxic reagents from the process or the reduction of their concentration.
采用电化学蚀刻法制备钛表面阳极氧化膜
研究了钛在含氟有机水混合电解质中的阳极极化行为。为电极过程构建的极化曲线使我们得出结论,在特定的电解质中,几个过程的同时行为是可能的,这些过程包括金属的化学蚀刻,由于其与溶液组分的相互作用,极化条件下的电化学溶解以及由于阳极氧化而形成的氧化膜。在这种情况下,一种或另一种类型的过程的普遍性是由电解质组成和电解参数定义的。所获得的数据为开发新的联合蚀刻方法提供了基础,该方法提供了钛表面的均匀化,同时消除了过程中的有毒试剂或降低了它们的浓度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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