Energy Transfer in LiSrPO4 Doped with Pr3+ and Co-Doped with Dy3+, Sm3+

E. Trofimova, I. Romet, V. Pustovarov, M. Kirm, S. Omelkov, M. Bettinelli
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引用次数: 1

Abstract

The study deals with the investigation of luminescence properties and energy transfer processes in LiSrPO4 doped with Pr3+ and co-doped with Dy3+ or Sm3+. Ultraviolet (UV) and vacuum ultraviolet (VUV) excited emission and excitation spectra are studied, as well as pulsed cathodoluminescence spectra in wide temperature range 5–295 K. In both compounds, Pr3+ plays a role of a sensitizer of co-dopant ion emission in visible range via energy transfer processes. Studies of the photoluminescence excitation spectra show rather complex energy transfer mechanisms and defect emission influence on the emission spectra. The use of Pr3+ in pair with Dy3+, Sm3+ and other ions may enhance the luminescence properties of a compound via increased absorption in UV range, enhancing its suitability to be used as possible white light emitting diodes (W-LEDs) phosphors.
Pr3+掺杂和Dy3+、Sm3+共掺杂LiSrPO4的能量转移
研究了掺杂Pr3+和共掺杂Dy3+或Sm3+的LiSrPO4的发光特性和能量转移过程。研究了紫外(UV)和真空紫外(VUV)激发发射光谱和激发光谱,以及5 ~ 295 K宽温度范围内的脉冲阴极发光光谱。在这两种化合物中,Pr3+通过能量转移过程在可见光范围内发挥了共掺杂离子发射的敏化剂作用。光致发光激发光谱的研究表明,其能量传递机制较为复杂,缺陷发射对发射光谱的影响较大。Pr3+与Dy3+、Sm3+等离子配对使用,可以通过增加紫外吸收来增强化合物的发光性能,从而增强其作为白光发光二极管(w - led)荧光粉的适用性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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