A flexible glucose biofuel cell with porous polypyrrole electrodes modified with enzymes

Ryohei Sano, Jun Yamasaki, Hideaki Goto, Takuma Ishida, Yusuke Fujimagari, Kazuki Hoshi, Y. Fukushi, Y. Nishioka
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Abstract

We fabricated a totally flexible glucose biofuel cell containing conductive porous polypyrrole (PPy) electrodes modified with enzymes. The porous PPy films were galvanostatically synthesized and glued on a polyimide flexible sheet to form porous conductive electrodes. The surface of anode was modified with glucose oxidase and a ferrocene mediator, and the surface of cathode was deposited with bilirubin oxidase. The generated power in the biofuel cell with PPy electrodes was 5 times higher than that with carbon electrodes.
具有酶修饰的多孔聚吡咯电极的柔性葡萄糖生物燃料电池
我们制备了一种完全柔性的葡萄糖生物燃料电池,该电池含有经酶修饰的导电多孔聚吡咯(PPy)电极。采用恒流合成多孔聚吡啶薄膜,并将其粘接在聚酰亚胺柔性片上形成多孔导电电极。阳极表面用葡萄糖氧化酶和二茂铁介质修饰,阴极表面用胆红素氧化酶沉积。使用PPy电极的生物燃料电池产生的功率是使用碳电极的5倍。
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