Preparation of Fe-based soft magnetic composites with high Bs by acidic bluing coating

G. Zhao, C. Wu, M. Yan
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Abstract

Fe-based soft magnetic composites (SMCs) are technologically important due to their unique properties such as satisfactory magnetic performance and low loss for high frequency applications. Insulation coating of the ferromagnetic powders is critical in the preparation of SMCs. While traditional phosphate treatment allows surface passivation of the Fe powders, the obtained phosphate coating layers are non-magnetic, resulting in decreased saturation magnetization. Consequently, it is essential to develop SMCs with both high flux density and low loss. In this work, acidic bluing method has been used to grow Fe3O4 layers as insulation coating on the surfaces of iron powders. As Fe3O4 is a ferromagnetic material with high electrical resistivity, the effect of magnetic dilution can be avoided.
酸性蓝涂法制备高硼铁基软磁复合材料
铁基软磁复合材料(SMCs)由于其独特的性能,如令人满意的磁性和低损耗,在高频应用中具有重要的技术意义。铁磁粉末的绝缘涂层是制备SMCs的关键。而传统的磷酸盐处理允许铁粉的表面钝化,得到的磷酸盐涂层是无磁性的,导致降低饱和磁化。因此,开发高磁通密度和低损耗的SMCs至关重要。本研究采用酸性发蓝法在铁粉表面生长Fe3O4层作为绝缘涂层。由于Fe3O4是一种具有高电阻率的铁磁性材料,可以避免磁稀释的影响。
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