Quality Control Methods for Macromonomers of Polycarboxylate Superplasticizer Based on Infrared Spectroscopy

Yanna Shi, Y. Ke, Xiaofang Zhang, Yunhui Fang
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Abstract

Three kinds of methods for spectrum processing, peak height method, peak area method and correlation coefficient method, were used to study the two kinds of macromonomers of polycarboxylate superplasticizer, HPEG and TPEG. The research found that it is more accurate to use the correlation coefficient method to control the quality of the two kinds of macromonomers. The verification results showed that they were consistent with the test results of the cement paste. The macro quality control standards for the HPEG and TPEG were initially established. The important reference data and evaluation basis for the HPEG and TPEG were provided, and the quality control values of the HPEG and TPEG were 0.9106 and 0.9070, respectively.
基于红外光谱的聚羧酸酯高效减水剂大单体质量控制方法
采用峰高法、峰面积法和相关系数法三种光谱处理方法,对聚羧酸酯型高效减水剂的两种高分子单体HPEG和TPEG进行了研究。研究发现,用相关系数法对这两种高分子单体的质量控制更为准确。验证结果与水泥浆体试验结果一致。初步建立了HPEG和TPEG的宏观质量控制标准。为HPEG和TPEG提供了重要的参考数据和评价依据,HPEG和TPEG的质量控制值分别为0.9106和0.9070。
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