Reason Analysis and Control Strategy on Operation Corrosion in Direct Air-cooled Condensers (ACC)

Yuqiang Deng, Z. Ye, Dongdong Qi, Fei Song, Dongmei Wang, Shaoyong Zhang, Guobao Cai, Jiguang Zhang, Wei Tu
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Abstract

The operation corrosion in direct air-cooled condensers (ACC) had been widespread in china. Various water treatment devices were used for condensate water in order to control feedwater iron concentration below the limit according to guidelines, however direct ACC operation corrosion still existed and needed a thorough solution. Ammonia has a lower partition coefficient in the initial condensate, as well acidic anions are concentrated in the initial condensate, thus the initial condensate has lower pH, which results in the above mentioned corrosion. To reduce the direct ACC operation corrosion, methods could be applied, such as dosing higher ammonia in feedwater or dosing some organic alkalizing reagent in exhaust steam as an auxiliary. Keywords—thermal power plant; direct air cooling unit; air condenser; operating corrosion; corrosion control; alkalizing agent
直接空冷冷凝器(ACC)运行腐蚀原因分析及控制策略
直接空冷式冷凝器的运行腐蚀问题在国内十分普遍。凝结水采用了各种水处理装置,使给水铁浓度按规定控制在限值以下,但直接ACC操作腐蚀仍然存在,需要彻底解决。氨在初始凝析液中的分配系数较低,酸性阴离子在初始凝析液中集中,因此初始凝析液的pH值较低,从而导致上述腐蚀。为了减少直接ACC操作的腐蚀,可以采用在给水中添加高氨或在排汽中添加有机碱化剂作为辅助剂的方法。关键词:火电厂;直接空冷机组;空气冷凝器;操作腐蚀;腐蚀控制;碱化剂
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