Comparison Between Flame Atomic Absorption and Microwave Plasma Atomic Emission Spectrometers in The Analysis of Gold Content

Bruna Eugênia Campos Vieira
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Abstract

The present work aims to compare the reading techniques of Flame Atomic Absorption and Microwave Plasma Atomic Emission Spectrometry. A total of 10 certified samples with the gold levels specified were chosen. After quantifying the gold content in the sampels of interest, the results were transcribed into tables, where the relative error of each of the samples in relation to the certified values and the coefficient of variation of the three aliquots of each standard were also calculated. The study certified the high rate of gold recovery through the Fire Assay and revealed the better performance of MP-AES in relation to FAAS under the reading conditions established by the authors, according to the existing scientific literature. It is concluded that the MP-AES has enough potential to be an alternative, or even to replace instruments commonly used in the quantification of elements, such as gold, provided that more studies emerge to test and prove its superiority.
火焰原子吸收与微波等离子体原子发射光谱法分析金的比较
比较了火焰原子吸收法和微波等离子体原子发射光谱法的读数技术。总共选择了10个具有指定黄金水平的认证样本。在对感兴趣的样品中的含金量进行量化后,结果被转录到表格中,其中每个样品相对于认证值的相对误差以及每个标准的三个等分的变异系数也被计算出来。根据现有的科学文献,该研究通过Fire Assay验证了金的高回收率,并揭示了MP-AES在作者所建立的读取条件下相对于FAAS具有更好的性能。结论是,MP-AES有足够的潜力成为一种替代品,甚至取代通常用于定量元素(如金)的仪器,只要有更多的研究出现来测试和证明其优越性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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