Twenty Years of Knudsen Effusion Mass Spectrometry: Studies Performed in the Period 1990-2010

Mirosław Miller, K. Armatys
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引用次数: 14

Abstract

Investigations carried out by Knudsen effusion mass spectrometry on metals, alloys, oxides, and fullerene systems in the period 1990-2010 are reviewed in the present paper. 362 original papers were published in this period by ca. 45 research groups thereby showing still large activity in this unique area. The fundamentals and recent developments of the method are briefly reported. Data to the systems studied, temperature ranges, vapour species identified in the equilibrium vapours and thermodynamic properties obtained in the study are reported. Important features of these studies are briefly discussed as well. Most of the vaporization studies by Knudsen effusion mass spectrometry carried out on alloys, oxides and fullerenes aimed at the determination of thermodynamic data of gaseous species and condensed phases. Many of the studied materials are of practical importance for modern technologies. The investigations should give information on thermal stability, volatility under different conditions (temperature, oxygen partial pressure, and gaseous impurities), oxidation resistance, reactivity etc.
二十年的Knudsen积液质谱分析:1990-2010年期间进行的研究
本文综述了1990-2010年间克努森液质谱法对金属、合金、氧化物和富勒烯体系的研究进展。在此期间,约有45个研究小组发表了362篇原创论文,从而表明在这一独特领域仍有大量活动。简要报告了该方法的基本原理和最新发展。报告了所研究系统的数据、温度范围、平衡蒸汽中确定的蒸汽种类和研究中获得的热力学性质。并简要讨论了这些研究的重要特点。克努森流体质谱法的汽化研究大多是针对合金、氧化物和富勒烯进行的,目的是测定气态和凝聚相的热力学数据。所研究的许多材料对现代技术具有实际意义。调查应提供热稳定性、不同条件下(温度、氧分压和气体杂质)的挥发性、抗氧化性、反应性等信息。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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