Recent Progress on Nitrogen-Rich Energetic Materials Based on Tetrazole Skeleton

IF 8.6 2区化学 Q1 Chemistry

Topics in Current Chemistry Pub Date : 2023-08-23 DOI:10.1007/s41061-023-00435-8

Bihai Chen, Han Lu, Jiayi Chen, Zhaoxu Chen, Shuang-Feng Yin, Lifen Peng, Renhua Qiu

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引用次数: 1

Abstract

Development of nitrogen-rich energetic materials has gained much attention because of their remarkable properties including large nitrogen content and energy density, good thermal stability, low sensitivity, good energetic performance, environmental friendliness and so on. Tetrazole has the highest nitrogen and highest energy contents among the stable azoles. The incorporation of diverse explosophoric groups or substituents into the tetrazole skeleton is beneficial to obtain high-nitrogen energetic materials having excellent energetic performance and suitable sensitivity. In this review, the development of high-nitrogen energetic materials based on tetrazole skeleton is highlighted. Initially, the property and utilization of nitrogen-rich energetic materials are presented. After showing the advantage of the tetrazole skeleton, the high-nitrogen energetic materials based on tetrazole are classified and introduced in detail. Based on different types of energetic materials (EMs), the synthesis and properties of nitrogen-rich energetic materials based on mono-, di-, tri- and tetra-tetrazole are summarized in detail.

Graphical Abstract

Abstract Image

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基于四唑骨架的富氮含能材料研究进展。

富氮含能材料因其氮含量和能量密度大、热稳定性好、灵敏度低、高能性能好、环境友好等显著性能而备受关注。在四唑骨架中掺入不同的爆炸基团或取代基有利于获得具有优异能量性能和合适灵敏度的高氮含能材料。综述了基于四唑骨架的高氮含能材料的研究进展。首先介绍了富氮含能材料的性质及其利用。在展示了四唑骨架的优点后，对基于四唑的高氮含能材料进行了详细的分类和介绍。基于不同类型的含能材料，详细总结了基于单、二、三和四唑的富氮含能材料的合成和性能。

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来源期刊

Topics in Current Chemistry 化学-化学综合

CiteScore

11.70

自引率

1.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science. Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community. In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.